Calculating the Detection Limits of Chamber-based Soil Greenhouse Gas Flux Measurements
- T. B. Parkin *a,
- R. T. Ventereab and
- S. K. Hargreavesc
- a USDA–ARS, National Lab. for Agriculture and the Environment, 2110 University Blvd., Ames, IA 50011
b USDA–ARS, Soil and Water Research Management Unit, 1991 Upper Buford Cir., 439 Borlaug Hall, St., Paul, MN 55108
c Dep. of Ecology, Evolution and Organismal Biology, Iowa State Univ., 253 Bessey Hall, Ames, IA, 50011. Mention of trade names or commercial products in this article is solely for the purpose of providing specific information and does not imply recommendation or endorsement by the U.S. Department of Agriculture. The USDA is an equal opportunity provider and employer. Assigned to Associate Editor Martin H. Chantigny
Renewed interest in quantifying greenhouse gas emissions from soil has led to an increase in the application of chamber-based flux measurement techniques. Despite the apparent conceptual simplicity of chamber-based methods, nuances in chamber design, deployment, and data analyses can have marked effects on the quality of the flux data derived. In many cases, fluxes are calculated from chamber headspace vs. time series consisting of three or four data points. Several mathematical techniques have been used to calculate a soil gas flux from time course data. This paper explores the influences of sampling and analytical variability associated with trace gas concentration quantification on the flux estimated by linear and nonlinear models. We used Monte Carlo simulation to calculate the minimum detectable fluxes (α = 0.05) of linear regression (LR), the Hutchinson/Mosier (H/M) method, the quadratic method (Quad), the revised H/M (HMR) model, and restricted versions of the Quad and H/M methods over a range of analytical precisions and chamber deployment times (DT) for data sets consisting of three or four time points. We found that LR had the smallest detection limit thresholds and was the least sensitive to analytical precision and chamber deployment time. The HMR model had the highest detection limits and was most sensitive to analytical precision and chamber deployment time. Equations were developed that enable the calculation of flux detection limits of any gas species if analytical precision, chamber deployment time, and ambient concentration of the gas species are known.Please view the pdf by using the Full Text (PDF) link under 'View' to the left.
Copyright © 2012. . Copyright © by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America, Inc.