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This article in JEQ

  1. Vol. 9 No. 4, p. 587-592
    Received: Jan 23, 1980
    Published: Oct, 1980



Effect of Nitrification on Movement of Trace Metals in Soil Columns1

  1. Fu-Hsian Chang and
  2. F. E. Broadbent2



Soil column experiments were conducted with sludge-treated and untreated samples of two soils, Omni silty clay and Delhi loamy sand, to determine whether protons generate during the nitrification process would affect the mobility of the trace metals Cd, Cr, Cu, Mn, Ph, and Zn. Columns 5 cm × 100 cm were leached bi- or tri-weekly with 7.5-cm applications of solutions of CaCl2, NH4Cl, or KCl. Trace metals in effluents from the columns were analyzed after each application of leaching solution. After 11 applications over a period of several months the columns were sectioned and the vertical distribution of 2N HCl-extractable metals determined.

Average concentrations of metals in column effluents were well below 1 ppm in all cases except Zn eluted from untreated Delhi loamy sand where 20 mM NH4Cl or KCl leaching solutions produced effluent concentrations slightly above 1 ppm. There was evidence of nitrification affecting movement of several of the metals, particularly in the cases of Mn, Zn, Cu, and Cd in the untreated Delhi soil. The presence of sludge had a pronounced stabilizing influence of Cd and Zn, and to a lesser degree on other metals, probably as a result of organo-metal complexes.

Much of the input labeled NH4-N was denitrified, as shown by recoveries of N ranging from 14 to 20% in the Omni soil and 40 to 78% in the Delhi soil. Proton generation during nitrification was, thus, partially offset by neutralization during denitrification. It was concluded that nitrification had relatively little effect on metal mobility under the conditions of the experiment.

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