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This article in SSSAJ

  1. Vol. 33 No. 1, p. 54-59
     
    Received: May 3, 1968
    Accepted: July 31, 1968


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doi:10.2136/sssaj1969.03615995003300010018x

Micronutrient Cation Complexes in Soil Solution: III. Characterization of Soil Solution Ligands and their Complexes with Zn2+ and Cu2+1

  1. H. R. Geering and
  2. J. F. Hodgson2

Abstract

Abstract

At least three groups of compounds were found to complex Zn2+ and Cu2+ in soil solution from the A horizon of a Williamson silt loam. A nondialyzable fraction of soil solution ligands had a poorly defined acid dissociation, pKa, ranging from 3 to 4.7. The dialyzable fraction had acid dissociation constants of 4.5 and 9.5, which were attributed to aliphatic and amino acids, respectively. The equivalent concentration of the nondialyzable acid fraction was only 1/40 that of the dialyzable fraction, but was more effective in complexing Zn and Cu in the soil solution. The average metal/ligand ratio was equal to unity in complexes of both the dialyzable and nondialyzable fractions with Zn2+ and Cu2+. Estimated, log10 (average formation constants) of the nondialyzable-metal complexes were calculated on the basis of titratable acidity as 4.3 ± 0.1 and 5.5 ± 0.1 for Zn2+ and Cu2+, respectively.

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