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This article in SSSAJ

  1. Vol. 51 No. 3, p. 801-806
    Received: Nov 29, 1985



Extraction and Determination of Sulfur in Organic Horizons of Forest Soils1

  1. D. G. Maynard,
  2. Y. P. Kalra and
  3. F. G. Radford2



Little information exists on the accuracy, precision, and make-up of extractable S in surface organic horizons of forest soils. Eight extractants (H2O, 0.01 M CaCl2, 0.01 M KCl, 0.01 M LiCl, 0.003 M NH4OAc, 0.003 and 0.01 M NH4Cl, and 500 mg P L−1 as Ca(H2PO4)2·H2O) were evaluated for the extraction and determination of SO4-S and total extractable S in surface organic horizons of five forest soils. The analyses for SO4-S and total extractable S were performed by ion chromatography (IC) and inductively coupled plasma atomic emission spectrometry (ICP-AES), respectively. Each of the weak salt extractants removed similar amounts of SO4-S and total extractable S. Water was the least desirable extractant because it removed more organic S than the salt extractants, was the most variable for IC analysis, and produced inconsistent results. The 0.01 M NH4Cl extractant, however, was found to be the most consistent extractant. The precision ranged from 3.7 to 8.9% for the IC analyses excluding the aspen (Populus tremuloides Michx.) sample and from 1.9 to 8.4% for the ICP-AES analyses. Poor precision in the SO4-S determination of the aspen organic horizon was due to the elution of an unidentified peak adjacent to the S peak. Quantitative recoveries from 102 to 108% and from 97 to 108% were obtained in the 0.01 M NH4Cl extract by the IC and ICP-AES methods, respectively. The effect of varying solution to soil ratios was also determined for 0.01 M NH4Cl. The 10:1 solution to soil ratio was the most consistent. Ratios <10:1 had significantly lower concentrations of extractable S and SO4-S for three soils and caused logistical problems in the laboratory (i.e., slower filtering, more sample required) because of the low solutin-to-soil ratio. Storage of airdried material at room temperature (20 ± 4 °C) for 1.5 yr resultd in increased total extractable S and SO4-S concentrations.

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